カワムラ　クニオ   KAWAMURA Kunio   川村　邦男    所属   広島修道大学  人間環境学部    職種   教授
言語種別	英語
発行・発表の年月	1987/12
形態種別	学術論文
査読	査読有り
標題	Kinetics of pyridine derivatives as accelerators for the incorporation reaction ofcadmium(II) into porphyrin and association behaviors of the accelerators with porphyrin
執筆形態	共著
掲載誌名	Chem. Lett.
掲載区分	国内
巻・号・頁	16(12),pp.2265-2268
担当範囲	Corresponding anthor
著者・共著者	◎Kunio Kawamura, Hiroshi Kasahara, Shukuro Igarashi, Takao Yotsuyanagi
概要	Incorporation reaction rate constants of cadmium(II) ion into 5,10,15,20-tetrakis(4-sulphonatophenyl)porphine (H2tpps) in the presence of 8 kinds of pyridine derivatives as accelerators were determined. And association constants for 5 kinds of the accelerators with H2tpps were also determined; the logarithmic values of which were proportional to the number of pyridine rings. The association constant is found to be one of the most important factors for controlling the acceleration effect.